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产品基本信息
产品编号：E891540
产品名称：(1-[Ethoxycarbonyl]ethylidene)triphenylphosphoran
产品CAS：5717-37-3
规格含量：10g
产品价格：面议
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产品详细介绍
标准品编号:
E891540
名称:
(1-[Ethoxycarbonyl]ethylidene)triphenylphosphoran
别名:
((Ethoxycarbonyl)ethylidene)triphenylphosphorane; (Carbethoxyethylidene)triphenylphosphorane; 1-(Ethoxycarbonyl)ethylidenetriphenylphosphorane; 1-Carboethoxyethylidenetriphenylphosphorane; 2-(Triphenylphosphoranylidene)propanoic Acid Ethyl Ester; Ethyl 2-(Triphenylphosphoranylidene)propanoate; Ethyl 2-(Triphenylphosphoranylidene)propionate; Ethyl Methyltriphenylphosphoranylideneacetate; NSC 76468; Triphenyl-α-ethoxycarbonylethylidenephosphorane; [α-(Ethoxycarbonyl)ethylidene]triphenylphosphorane; α-(Ethoxycarbonyl)ethylenetriphenylphosphorane;
CAS号:
5717-37-3
分子式:
C₂₃H₂₃O₂P
外观:
Pale Yellow to 淡黄色固体
熔点:
>147ºC (dec.)
分子量:
362.4
储存:
Hygroscopic, 冰箱保存, under inert atmosphere
溶解度:
Chloroform (Slightly), Methanol (Slightly)
种类:
Building Blocks; Pharmaceutical/API Drug Impurities/Metabolites;
应用:
(1-[Ethoxycarbonyl]ethylidene)triphenylphosphoran, is a Horner–Wadsworth–Emmons reagent. It can be used for olefination. It can also be utilized for the synthesis of more complex compounds, such as (29S,37S)-isomer of malevamide E, a potent ion-channel inhibitor.
参考文献
Gajula, P., et al.: Org. Biomol. Chem., 11, 257 (2013); Naito, T., et al.: Chem. Pharm. Bull., 44, 624 (1996), Hata, A., et al.: Mol. Pharmacol., 67, 640 (2005),
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