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产品编号：B430370
产品名称：2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
产品CAS：98327-87-8
规格含量：25g
产品价格：面议
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产品详细介绍
标准品编号:
B430370
名称:
2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene
别名:
1,1'-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine]; [1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]; (±)-BINAP; 2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthyl; 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl; BINAP; [1,1'-Binaphthalene]-2,2'-diylbis[diphenylphosphine]; rac-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl; rac-BINAP
CAS号:
98327-87-8
分子式:
C₄₄H₃₂P₂
外观：
白色至白色固体
熔点:
>200ºC (dec.)
分子量:
622.67
储存:
Room Temperature, under inert atmosphere
溶解度:
Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),
种类:
Building Blocks; Catalyst;
应用:
2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene is a powerful chiral auxiliary that is used as a homogeneous catalyst in some asymmetric chemical syntheses. 2,2'-Bis(diphenylphosphino)-1,1'-dinaphthalene is utilized for its high enantioselectivity and is used as a ligand to create coordination complexes.
文献
DiBari, L., et al.: J. Am. Chem. Soc., 121, 7998 (1999); Hatano, M., et al.: J. Am. Chem. Soc., 130, 16858 (2008); Kitamura, M., et al.: Tetrahedron Lett., 32, 4163 (1991); Shimada, T., et al.: J. Org. Chem., 66, 8854 (2001)
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