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产品编号：C371428
产品名称：Chlorobis(cyclooctene)iridium(I) Dimer
产品CAS：12246-51-4
规格含量：5mg
产品价格：面议
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产品详细介绍
标准品编号:
C371428
名称:
Chlorobis(cyclooctene)iridium(I) Dimer
别名:
di-​μ-​chlorotetrakis[(1,​2-​η)​-​cyclooctene]​di-Iridium; Cyclooctene, iridium complex; Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]diiridium; Bis((μ-chloro)bis(cyclooctene)iridium); Bis(chlorobis(cyclooctene)iridium); Bis(cyclooctene)iridium chloride dimer; Bis(μ-chloro)bis(bis(cyclooctene)iridium); Bis(μ-chloro)tetrakis(cyclooctene)diiridium; Bis[chlorobis(η2-cyclooctene)iridium]; Chlorobis(cyclooctene)iridium dimer; Di-μ-Chlorotetrakis(cyclooctene)diiridium; Di-μ-chlorotetrakis(η2-cyclooctene)diiridium; Dichlorotetrakis(cyclooctene)diiridium; Tetrakis(η2-cyclooctene)dichlorodiiridium
CAS号:
12246-51-4
分子式:
C₃₂H₅₆Cl₂Ir₂
分子量:
896.13
类别:
Building Blocks; Catalyst;
应用:
Chlorobis(cyclooctene)iridium(I) dimer is a catalyst used to promote the pyridyl-​directed ortho-​CH and ortho-​CBr activations of the Ph substituent of 2-​(2-​bromophenyl)​pyridine. It is also used to catalyze reductive nucleophilic additions to secondary amides.
参考文献
Boudreault, P.; et al.: Organometallics, 37, 3770 (2018); Takahashi, Y.; et al.: Org. Lett., 20, 5705 (2018).
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