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产品基本信息
产品编号：D360500
产品名称：(Diacetoxyiodo)benzene
产品CAS：3240-34-4
规格含量：50g
产品价格：面议
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产品详细介绍
标准品编号:
D360500
名称:
(Diacetoxyiodo)benzene
别名:
(Dihydroxyiodo)benzene; (Diacetoxyiodo)benzene; BAIB; Bis(acetato)phenyliodine; Bis(acetato-κO)phenyliodine; Diacetoxy(phenyl)iodine; Iodobenzene Diacetate; Iodophenyl Diacetate; Iodosobenzene Diacetate; Iodosylbenzene Diacetate; NSC 226375; NSC 23801; PIDA; Phenyliodine Diacetate; Phenyliodine(III) Diacetate; Phenyliodo Diacetate; Phenyliodonium Diacetate; Phenyliodoso Acetate; Phenyliodoso Diacetate; Phenyliodosyl Diacetate; [Bis(acetoxy)iodo]benzene; Iodosodiacetate Benzene;
CAS号:
3240-34-4
分子式:
C₁₀H₁₁IO₄
外观:
白色至白色固体
熔点:
161-163°C
分子量:
322.1
储存:
Amber Vial, -20°C Freezer, Under inert atmosphere
溶解性:
DMSO (Slightly), Ethyl Acetate (Slightly, Heated), Methanol (Slightly)
稳定性:
Light and Moisture sensitive
种类:
Building Blocks; Miscellaneous;
应用:
(Diacetoxyiodo)benzene is a hypervalent iodine reagent that is used in conjunction with catalytic amount of sodium azide in acetonitrile, which enables oxidative decarboxylation of 2-aryl carboxylic acid into the corresponding aldehydes, ketones and nitriles.
参考文献
Telvekar, V.N., et al.: Synlett., 2778 (2012); Liu, W.B., et al.: Beilstein. J. Org. Chem., 8, 244 (2012);
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